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Development of an Overall Water Quality Index (OWQI) for Surface Water in Indian Context

Surjeet Singh1 , N. C. Ghosh1 , Gopal Krishan1 , Ravi Galkate2 , T. Thomas2 and R. K. Jaiswal2

1 National Institute of Hydrology, Roorkee, 247667 Uttarakhand India

2 National Institute of Hydrology, Ganga Plains South Regional Centre, Bhopal, 462042 India

DOI: http://dx.doi.org/10.12944/CWE.10.3.12

A number of water quality indices based on classification criteria, sub-indices and aggregation function have been developed by the researchers for categorizing the water quality for different uses. In the present study, a general Overall Water Quality Index (OWQI) is developed to classify the surface water into five categories, viz. excellent, good, fair, poor and polluted. For this purpose, the concentration ranges have been defined on the basis of the Indian Standards (IS) and Central Pollution Control Board (CPCB) standards also taking into account other International standards of World Health Organization (WHO) and European Commission (EC). Sixteen parameters are selected based on social and environmental impact and weights are assigned on their relative importance to impact the quality of water. The proposed index improves understanding of water quality issues by integrating complex data and generates a score which describes the status of water quality. The proposed index will be very useful for the water management authorities to maintain good health of surface water resources.


OWQI; Water quality;Standards; Sub-indices; Sagar Lake

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Singh S, Ghosh N. C, Krishan G, Galkate R, Thomas T, Jaiswal R. K. Development of an Overall Water Quality Index (OWQI) for Surface Water in Indian Context. Curr World Environ 2015;10(3) DOI:http://dx.doi.org/10.12944/CWE.10.3.12

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Singh S, Ghosh N. C, Krishan G, Galkate R, Thomas T, Jaiswal R. K. Development of an Overall Water Quality Index (OWQI) for Surface Water in Indian Context. Available from: http://www.cwejournal.org/?p=12994


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Article Publishing History

Received: 2015-10-12
Accepted: 2015-10-29

Introduction

The quality of water is defined in physical, chemical, biological forms in each category and the water quality parameters are selected on the basis of their intended use. A number of sites for the water quality monitoring create voluminous information and results in complexity to categorize the quality of water for various purposes. Such classifications are generally used for comparison of quality of water on individual parameter basis as per the national and international standards. Even after comparison, it is extremely difficult to arrive at any conclusion due to a number of parameter values in different ranges. In order to overcome such difficulties an Overall Water Quality Index (OWQI) is developed in this paper based on sixteen parameters that are generally used for drinking purpose under the surface water category. These parameters include turbidity, colour, total dissolved solids (TDS), pH, dissolved oxygen (DO), biochemical oxygen demand (BOD), secchi depth, hardness, chloride, fluoride, nitrate, total phosphate, iron, sulphate, arsenic and total coliform.

In general, the major objective of water quality assessment is to determine the fulfillment of defined objectives; to describe water quality at regional, national or international scales, and also to investigate trends in time1 so that it can be classified within the respective regulatory standards2 for various intended purposes such as potable water, agricultural, recreational and industrial water uses3. A number of water quality indices have been developed by various researchers but many of them have some kind of flaws. Bharti and Katyal (2011)4 reviewed a number of water quality indices for surface water vulnerability assessment. A comparison of various water quality indices was made by Abbasi (1999)5 and an overview of various types of sub-indices, aggregation functions and flaws is presented in Table 1.

Table 1: Comparison of various water quality indices (Abbasi, 1999)5

S. N.

Index

Sub-Indices

Aggregation Function

Flaws

1

Horton (1965)6

Segmented linear (step functions)

Weighted sum multiplied by 2 Dischotomous term

Eclipsing region

2

Brown et al. (1970)7

Implicit non-linear

Weighted sum

Eclipsing region

3

Landwehr (1976)8

Implicit non-linear

Weighted product

Non-linear

4

Parti et al. (1971)9

Segmented non-linear

Weighted sum (arithmetic mean)

Eclipsing region

5

Mc Duffie & Haney (1973)10

Linear

Weighted sum

Eclipsing region

6

Dinius (1972)11

Non-linear

Weighted sum

Eclipsing region

7

Dee et al. (1973)12

Implicit non-linear

Weighted sum

Eclipsing region

8

O’Connor’s (1972)13

Implicit non-linear

Weighted sum

Eclipsing region

9

Deininger & Landwehr (1971)14

Implicit non-linear

Weighted sum & geometric mean

Eclipsing region & non-linear

10

Walski & Parker (1974)15

Non-linear

Weighted product Geometric mean

Non-linear

11

Stoner (1978)16

Non-linear

Weighted sum

 

12

Nemerow & Sumitomo (1970)17

Segmented linear

Root mean square of max. & arithmetic mean

- ve value

13

Smith (1987)18

Multiple types

Minimum operator

- ve value

14

Viet & Bhargava (1998)19

Multiple types

Weighted product

- ve value

 

Sargaonkar & Deshpande (2003)3 and Boyacioglu (2007)1 have developed two water quality indices in the exponential form and in linear form, respectively during the last decade but the coliform index developed by Boyacioglu (2007)1 gives erroneous value of index in the parameter range of 5000 to 50000, while in case of Sargaonkar & Deshpande (2003),3 some eclipsing problem occurs in the indices of DO, hardness, nitrate and coliform.

Keeping in view, the flaws in the above indices, an Overall Water Quality Index (OWQI) is developed by considering sixteen water quality parameters which covers physical, chemical and biological aspects of water. The concentration ranges, for this purpose, have been defined in Indian Standards (IS) and Central Pollution Control Board (CPCB) standards also taking into account International standards of World Health Organization (WHO) and European Commission (EC). This OWQI helps in understanding the quality of water by integrating the complex voluminous data and generates a score to describe the status of water quality. Such indices will prove very helpful for environmentalists, decision makers and field engineers in maintaining good health of surface water resources.

Methodology

The general methodology for the development of a water quality index can be summarized in the following four steps:

Parameter Selection - Selection of suitable/concerned water quality parameter.

Development of Sub-indices Function - Transformation of concentration of water quality parameters into mathematical equations.

Assignment of Weights - Deciding suitable weights of various selected water quality parameters.

Aggregation of Sub-indices to Construct an Overall Index – Construction of an overall water quality index (OWQI).

Selection of Water Quality Parameters

In India, Indian Standards (IS 10500: 1991) and Central Pollution Control Board (CPCB) standards govern the quality of water for various uses. Based on Indian and other standards, total sixteen parameters, viz. turbidity, colour, TDS, pH, DO, BOD, secchi depth, total hardness, chloride, fluoride, nitrate, total phosphate, iron, sulphate, arsenic and total coliform are considered significant to affect the surface water quality. For all these parameters, a class classification criterion has been devised to categorize the quality of water into five classes. These classes include excellent, good, fair, poor and heavily polluted. The proposed water quality classification criteria along with class and index score are given in Table 2.

Table 2: Proposed water quality classification criteria

S.N.

Parameters

Unit

Classes

     

Excellent

Good

Fair

Poor

Heavily Polluted

 Index Score

95-100

75-94

50-74

25-49

0-24

1

Turbidity

NTU

5

10

25

250

>250

2

Colour

Hazen Unit

10

15

50

175

>175

3

Total Dissolved Solids

mg/L

500

1000

1500

3000

>3000

4

pH

-

6.5-8.5

6.0 - 6.4

 &

8.6 - 9.0

5.5 - 5.9 &

9.1 - 9.5

< 5.5

&

> 9.5

< 5.5

&

> 9.5

5

DO

mg/L

8

6

4

2

<2

6

BOD

mg/L

2

3

5

7

>7

7

Secchi Depth

m

>=10

8.5

5

2.5

<0.85

8

Total Hardness

mg/L

< 300

400

500

600

>600

9

Chloride

mg/L

200

250

600

800

>800

10

Fluoride

mg/L

0.7-1.5

1.6

1.7

2

>2

11

Nitrate

mg/L

10

20

50

100

>100

12

Total Phosphate

mg/L

0.02

0.16

0.4

0.65

>0.65

13

Iron

mg/L

0.1

0.3

0.5

1

>1

14

Sulphate

mg/L

25

150

250

400

1000

15

Arsenic

mg/L

0.005

0.01

0.05

0.1

0.2

16

Total Coliform

MPN

50

500

5000

50000

>50000


Development of Sub-Indices Function

Sub-indices functions are basically the equations that transform the concentration ranges into the index score through mathematical equations. These scores are then further converted to a common scale based on their relative importance to impact the quality of water. These sub-indices function are developed based on the water quality standards and their concentrations to meet in particular range. For this purpose, mathematical expressions were fitted for each parameter to obtain the sub-index equations as given in Table 3. In this index, the corresponding variation between the range of parameter and index is kept uniform to provide more accurate value of indices.

Table 3: Development of sub-indices function for various parameters

S. N.

Parameter

Range of Parameter

Sub-Index Function

1

Turbidity

0 - 5

Y=100

6 - 10

Y=-4*X+115

11 - 25

Y=-1.667*X+91.67

26 - 250

Y=-0.111*X+52.78

> 250

Y=-0.1*X+50

2

Colour

0 - 10

Y=100

11 - 15

Y=-4*X+135

16 - 50

Y=-0.7143*X+85.71

> 50

Y=-0.2*X+60

3

TDS

0 - 500

Y=100

501 - 1000

Y=-0.2*X+195

1001 - 1500

Y=-0.0278*X+91.67

1501 - 3000

Y=-0.0167*X+75

> 3000

Y=-0.0083*X+50

4

pH

6.5 - 8.5

Y=100

6.0 - 6.4 & 8.6 - 9.0

Y=50

5.5 - 5.9 & 9.1 - 9.5

Y=25

< 5.5 & > 9.0

Y=0

5

DO

8 and above

Y=100

6 - 7.9

Y=10*X+15

0 - 5.9

Y=12.5*X

6

BOD

< 2

Y=100

2 - 2.9

Y=-20*X+135

3 - 7

Y=-12.5*X+112.5

> 7

Y=-5*X+60

7

Secchi Depth

10 and above

Y=100

< 10

Y=100*LOG(0.90*X+1)

8

Total Hardness

100 - 300

Y=100

301 - 400

Y=-0.2*X+155

> 400

Y=-0.25*X+175

9

Chloride

200 and below

Y=100

201 - 250

Y=-0.4*X+175

251 - 600

Y=-0.0714*X+92.86

> 800

Y=-0.125*X+125

10

Fluoride

0.7 - 1.2

Y=100

1.6 - 2.0

Y=-260.8*LN(X)+205.38

< 0.7 & > 2.0

Y=0

11

Nitrate

10 and below

Y=-0.5*X+100

11 - 20

Y=-2*X+115

21 - 50

Y=-0.8333*X+91.67

51-100

Y=-0.5*X+75

> 100

Y=-0.25*X+50

12

Total Phosphate

0.020 and below

Y=-250*X+100

0.021 - 0.160

Y=-142.857*X+97.86

0.161 - 0.40

Y=-104.1667*X+91.67

0.40 - 0.65

Y=-100*X+90

> 0.65

Y=-250*X+187.5

13

Iron

0.10 and below

Y=-50*X+100

0.11 - 0.30

Y=-100*X+105

0.31 - 0.50

Y=-125*X+112.5

0.50 - 1.0

Y=-50*X+75

> 1.0

Y=-25*X+50

14

Sulphate

0 - 25

Y=100

26 -150

Y=-0.16*X+99

151 - 250

Y=-0.25*X+112.5

251 - 400

Y=-0.1667*X+91.67

401 - 1000

Y=-0.0156*X+31.25

15

Arsenic

0 - 0.005

Y=100

> 0.005 - 0.01

Y=-4000*X+115

> 0.01 - 0.05

Y=-625*X+81.25

> 0.05 - 0.1

Y=-500*X+75

> 0.1 - 0.2

Y=-20.833*X+27.08

16

Total

 Coliform

0 - 50

Y=-0.1*X+100

51 - 500

Y=-0.0444*X+97.22

501 - 5000

Y=-0.0056*X+77.78

5001 - 50000

Y=-0.0006*X+52.78

> 50000

Y=-0.0005*X+50


Assignment of Parameter Weights

Selection of parameter weight is one of the most important tasks. Therefore, due emphasis should be given to decide the weight of each parameter. The parameter which greatly impacts the quality of water shall be given higher weight and vice-versa. These weights have been decided based on the judgment of the authors and the experience gained from the literature. The weight factors of all the sixteen parameters range from 1 to 4 and are presented in Table 4.

Table 4: Assignment of significance weight to the water quality parameter

Sl. No.

Parameter

Weight Factor

1

Turbidity

1

2

Colour

2

3

Total Dissolved Solids

3

4

pH

1

5

DO

4

6

BOD

2

7

Secchi Depth

3

8

Total Hardness

1

9

Chloride

1

10

Fluoride

3

11

Nitrate

3

12

Total Phosphate

2

13

Iron

3

14

Sulphate

2

15

Arsenic

4

16

Fecal Coliform

4

 

Total weight

39


Aggregation of sub-indices - Overall Water Quality Index (OWQI)

In order to gauge the influence of each individual parameter on a common single scale, the score generated by each parameter was averaged-out. The following weighted average aggregation function is used for this purpose.

Formula1

where  wi = weight of the ith water quality parameter

Yi = sub-index value of the ith parameter

Based on the status of water quality, the index value range from 0 to 100 and is classified into five categories: heavily polluted (0-24), poor (25-49), fair (50-74), good (75-94) and excellent (95-100). The status of water corresponding to different OWQI values is presented in Table 5. If the index goes down, then it indicates that some of the water quality parameters are being affected due to any particular reason and suitable measures are needed to further improve the quality of water. Thus this index may be used as a guiding rule in management of quality of surface water resources.

Table 5: OWQI and corresponding class and status of water quality

Class

OWQI Value

Status of Water

Heavily Polluted

0 - 24

Unsuitable for All Purposes

Poor

25 - 49

Special Treatment (Special Treatment)

Fair

50 - 74

Needs Treatment (Filtration & Disinfection)

Good

75 - 94

Acceptable

Excellent

95 - 100

Pristine Quality


Results and Discussion

The proposed OWQI is used as an application for the estimation of the index of water quality of sampling sites at Etawah on Yamuna River and Sagar Lake in India and Tahtali Reservoir in Turkey. The data of these sampling locations is taken from the published literature1,3,20 in which the study area are well described as shown in Figures 1 to 3. An MS Excel 2007 based computer programme is developed for computation of the water quality indices both individual parameter-wise and an overall index. This programme also suggests the quality class and status of water based on the OWQI.

Applications of OWQI for Assessment of Water Quality of Surface Water Bodies

The OWQI was computed for Etawah sampling location on the Yamuna River, Tahtali Reservoir and Sagar Lake. Yamuna River and Sagar Lake falls in the northern and central part of India, respectively while Tahtali Reservoir falls in City of Izmir in the western part of Turkey (Figures 1 to 3). The water quality indices are first estimated parameter-wise and then OWQI is computed for each location (Table 6 to 8).

Figure 1. Location map of sampling stations on  Yamuna River, India (Sargaonkar and Deshpande, 2003)3 


Figure 1: Location map of sampling stations on Yamuna
River, India (Sargaonkar and Deshpande, 2003)3
 

Click here to View figure

 

Figure 2. Location map of Tahtali Reservoir, Turkey (Boyacioglu, 2007)1 


Figure 2: Location map of Tahtali
Reservoir, Turkey (Boyacioglu, 2007)1

Click here to View figure

 

 Figure 3. Location map of Sagar Lake, India (Singh et al., 2009)20


Figure 3: Location map of Sagar
Lake, India (Singh et al., 2009)20

Click here to View figure


Table 6: Observed water quality and corresponding indices at Etawah on the Yamuna River (June, 1997)

 Parameter

Value

Indices

pH

8.65

50

Turbidity (NTU)

ND

100

Hardness (mg/L)

270

100

TDS (mg/L)

828

29

BOD5 (mg/L)

3

100

DO (mg/L)

7.9

94

Cl (mg/L)

213

90

NO3 (mg/L)

0.03

100

SO4 (mg/L)

75

87

Total Coliform (MPN/100ml)

2500

64

OWQI

79


Table 7: Observed water quality and corresponding indices for the Tahtali Reservoir

Parameter

Value

Indices

Arsenic (mg/L)

0.0058

92

Fluoride (mg/L)

0.792

100

Nitrate-N (mg/L)

5.84

97

DO (mg/L)

9.62

100

BOD5 (mg/L)

4.16

61

Total Phosphorous as PO4 (mg/L)

0.098

84

pH

8.18

100

Total Coliform (CFU/100ml)

170

90

OWQI

92


Table 8: Observed water quality and corresponding indices for the Sagar Lake

Parameter

Value

Indices

Secchi Depth (m)

0.23

8

pH

6.6

100

DO (mg/L)

4.37

55

Hardness (mg/L)

178.08

100

Chloride (mg/L)

63.34

100

Nitrate (mg/L)

9.76

95

Phosphate (mg/L)

0.44

46

Iron (mg/L)

1.71

7

BOD5 (mg/L)

11.4

3

TDS (mg/L)

378

100

OWQI

5


It is observed from Table 6 that the OWQI is 79 for the Etawah location on Yamuna River which indicates that the water falls in Class “Good” and the quality of water is “Acceptable”. Similar is the case for the Tahtali Reservoir where OWQI is 92 (Table 6) and the quality is relatively better. In case of Sagar Lake, it is seen from Table 7 that the OWQI is 54 and the corresponding quality class is “Fair” and this water needs treatment (filtration and disinfection) before any use.

Conclusions

In this paper an Overall Water Quality Index (OWQI) is developed to provide a simple tool for assessment of quality of surface water resources for drinking water supply. The OWQI is developed based on National and International standards by considering sixteen parameters covering physical, chemical and biological aspects of water. The application of OWQI is demonstrated for three different sampling locations and status of water is described on the basis of computed index. This OWQI provides a simpler means for the water quality assessment and is very useful of decision makers, planners and field engineers for maintaining good health of surface water resources. The proposed index can also be used as a decision support tool for the water quality management.

Acknowledgement

Authors thank Director, National Institute of Hydrology for all the support and encouragement.

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